There are seven vertices you can consider as the top of three possible isosceles triangles. For instance, if the vertices in circular order are called $X_1, X_2, \ldots, X_7$, the triangles $\Delta X_1X_4X_7$, $\Delta X_2X_4X_6$ and $\Delta X_3X_4X_5$ are all isosceles triangles. As such, the probability that a chosen triangle is an isosceles one equals:
$$\frac{{7 \choose 1} {3 \choose 1}}{7 \choose 3} = \frac{21}{35} = \frac{3}{5}$$