_Hint:_ Since $(a, b)$ divides the left hand side of $3a + 5b = 6$, it must divide the right hand side as well, so $(a, b) = 1, 2, 3$ or $6$. Now what does $(a, 3) = 1$ tell us about the possibilities?
_Hint:_ Since $(a, b)$ divides the left hand side of $3a + 5b = 6$, it must divide the right hand side as well, so $(a, b) = 1, 2, 3$ or $6$. Now what does $(a, 3) = 1$ tell us about the possibilities?