An example: semigroups with the identity $xy=x$ (semigroups of left zeroes).
Another exemple: Let $A,B$ be arbitrary sets, $S=A\times B$ with the multiplication $(a_1,b_1)(a_2,b_2)=(a_1,b_2)$ (a rectangular band).
Moreover, there is a description of medial semigroups (similarly to commutative ones): Every medial semigroup is a semilattice of medial archmedean semigroups. [A. Nagy, Special Classes of Semigroups. Springer, 2001; Theorem 9.3].