No, Japanese is full of voiced-unvoiced minimal pairs. There are minimal pairs even when the constituent morphemes are the same:
* mountains and rivers (dvandva compound)
* mountain rivers (modifier-head compound)
Dvandva compounds typically don't trigger rendaku, so the former is unvoiced. You can find plenty of other minimal pairs showing contrasts in voicedness, for example:
* mosquito
* moth
And so on. The important point is that native speakers hear these as clearly contrasting words, so it's a fundamental distinction in Japanese phonology. They are not homophonous in any sense.