The amount of fun from $x_1$ hours of work and $x_2$ hours of play is $x_1+2x_2$ "fun units." Or if you prefer, if an hour of work yields $k$ pleasure units, then an hour of play yields $2k$ pleasure units, and therefore $x_1$ hours of work and $x_2$ of play yield $kx_1+2kx_2$ pleasure units.
We want to maximize the amount of pleasure, so we want to maximize $kx_1+2kx_2$, or equivalently $x_1+2x_2$.
Your inequalities are fine, except for $x_2\ge 2x_1$, which was an incorrect attempt to express the fact that play is twice as much fun as work. That inequality should be removed from the list.