There are several things one needs to know to write down the jordan form. First, the algebraic multiplicity (degree of the root in the characteristic polynomial) tells you how many times that root apears on the diagonal. The geometric multiplicity is the dimension of the eigenspace inside the generalized eigenspace. The degree of the root in the minimal polynomial tells you the size of the largest jordan block.
Now the dimension of the nullspace of the $A-3I$ is the geometric multiplicity (dim eigenspace). Since the rank of that matrix is $4$, and it is a $6\times 6$ matrix, the nullspace must have dim $2$. So there are two jordan blocks corresponding to the eigenvalue $3$ and the largest one is $2\times 2$. Furthermore, the size of the largest jordan block for the eigenvalue $1$ is $2\times 2$. Can you write down the Jordan matrix?