Yes. To say :
> $\Gamma \vDash \phi$
means that :
> for every _valuation_ $v$, if $v$ satisfy every formula in $\Gamma$, then $v$ satisfy also $\phi$.
Thus, when we have : $\emptyset \vDash \phi$, this means that :
> for every valuation $v$, if $v$ satisfy all the formulae in $\emptyset$, then $v$ satisfy also $\phi$.
But there are **no** formulae in $\emptyset$ and thus the conditional in the definition of $\vDash$ is vacuously true.
Conclusion : every valuation $v$ satisfy $\phi$, and this amounts to say that $\phi$ is a _tautology_.