Note that The Inscribed Angle Theorem says that $\angle PQS$ is half the central angle of chord $\overline{PS}$ and $\angle SQR$ is half the central angle of chord $\overline{SR}$. Since $\overline{SQ}$ bisects $\angle PQR$, $\angle PQS = \angle SQR$. Therefore, $\overline{PS}=\overline{SR}$ by SAS (side-angle-side).