If you want the same format that you have specified
awk '{print NR "> " $s}' inputfile > outputfile
otherwise, though not standard, most implementations of the `cat` command can print line numbers for you (numbers padded to width 6 and followed by TAB in at least the GNU, busybox, Solaris and FreeBSD implementations).
cat -n inputfile > outputfile
Or you can use `grep -n` (numbers followed by `:`) with a regexp like `^` that matches any line:
grep -n '^' inputfile > outputfile