For the first question, note that you are saying that $x'$ and $x''$ are related if and only if _they have the **same** image under $f$_.
That keyword _same_ is a tell-tale sign that you have an equivalence relation. Just try to spell out the three properties, such as _for each $x$, is it true that $x$ and $x$ have the same image under $f$_ , and you'll see what I mean.
(By the way, you should see soon in your course that every equivalence relation arises this way.)
For the rest, just play around a bit - this is an exercise from which you can learn something only by trying to do it yourself. Starting with the reflexive/not reflexive part is probably sensible. Show us what you have tried, and you'll get help.