The author is proving that for $\sum_{j,i}\eta_{j,i}\mathbf B_{j,i}=0$ to hold, all $nm$ coefficients $\eta_{j,i}$ have to be zero, since that is the definition of linear independence. This is shown in groups of $m$ coefficients at a time, namely for fixed $k\in\\{1,\ldots,n\\}$ it is shown that $\eta_{k,1},\ldots,\eta_{k,m}$ must all be zero. The latter is achieved by applying both sides of the given identity to $\mathbf u_k$: the right hand side is zero of course, and the left hand side gives a linear combination of $\mathbf v_1,\ldots,\mathbf v_m$ with $\eta_{k,1},\ldots,\eta_{k,m}$ as coefficients; by the linear independence of $\mathbf v_1,\ldots,\mathbf v_m$ this is only possible if all those $m$ coefficients are zero, as desired.