In the general case, you'll have two angles, one for each axis.
The columns of the matrix are the images of the basis vectors. The rotation angles can be found via dot product:
For $$ A=\pmatrix {u_x & v_x \\\ u_y & v_y } $$ we’d have $$ \cos\theta_x=\frac {\mathbf e_x\cdot \mathbf u}{||\mathbf u||}=\frac{u_x}{\sqrt{u_x^2+u_y^2}} $$ and $$ \cos\theta_y=\frac {\mathbf e_y\cdot \mathbf v}{||\mathbf v||}=\frac{v_y}{\sqrt{v_x^2+v_y^2}} $$ This also gives you a way to tell if the matrix is a “rotation.”