I was using J.D. Murray's Asymptotic Analysis.
But it's not enough reading this book, he references Copson's book to complement his text in stuff that isn't proved in his text.
There are no solutions at the back, though.
But try asking your questions from the exercises here or in mathoverflow, I am sure you'll find someone who can help you.
Another good book (which I was reading it as a PDF) for Laplace transform theory (most books in control theory where you use Laplace transform don't go that much rigorous in the theory) is the book by M.G. Smith called Laplace transform theory. In this book there are worked out examples and exercises with answers but no detailed solutions.
Hope my answer helps you.