I) Generally stratification/rectification of a non-vanishing vector field is guaranteed locally by the local existence theorem for ODEs.
II) In OP's example, it is easiest to stratify/rectify the vector field $V$ in steps:
1. Choose first $$(y_1,y_2)~=~(\ln |x_1|,\ln|x_2| ).$$ Then the vector field becomes $$V ~=~ \frac{\partial}{\partial y_1} - 2\frac{\partial}{\partial y_2}$$ by the chain rule.
2. Next choose $$(y_1,y_2)~=~(z_1+f(z_2),-2z_1+g(z_2)),$$ so that the Jacobian is non-vanishing. Then the vector field $$V ~=~ \frac{\partial}{\partial z_1}$$ is stratified.