HINT:
The resultant ($R$) of any two forces say $P$ & $Q$ having angle $\alpha$ between them is given as $$R=\sqrt{P^2+Q^2+2PQ\cos \alpha}$$
The acute angle $\theta$ between the resultant & the force $P$ is given as $$\theta=\tan^{-1}\left|\frac{Q\sin \alpha}{P+Q\cos \alpha}\right|$$