Your answer is correct. Each card contributes an expected $\frac{4}{52}=\frac{1}{13}$ to the expected number of 5s and there are 6 cards so $$E(\text{number of 5s})=\frac{6}{13}\approx 0.4615$$ Any reasons why this answer seems wrong to you? A couple of simple point that might help to clear possible confusion:
The expected number of 5s is different from the probability of at least one five (because the expectation counts hands with 2 5s in them twice).
$E(X+Y)$ is _always_ equal to $E(X)+E(Y)$, it doesn't matter if $X$ and $Y$ are correlated, which is why it is often easier to calculate expected values than probabilities.