One side of the link (DCE), has to transmit the clock signal, which controls the data rate, and the other side (DTE) receives the clock signal.
R1 is DCE here:
interface Serial0/0/0
ip address 10.0.0.1 255.255.255.252
clock rate 2000000
R2 is DTE here:
interface Serial0/0/0
ip address 10.0.0.2 255.255.255.252
The difference between the two cables in packet tracer is just which side you click first:
 the side you click first will be the DCE, the second will be DTE
* With the **DTE cable** (red zigzag no clock) the side you click first will be DTE, the second will be DCE
Whichever way you do it, you'll see one side of the cable shows the clock symbol: this is the DCE.