The procedure explained in "Numeric approximations of hyperbolic systems of conservation laws" by Godlewsky and Raviart is applicable for strictly hyperbolic systems provided $U_L$ and $U_R$ are sufficiently close. The method in general is not applicable for any $U_L$ and $U_R.$
Strict hyperbolicity helps in solving Riemann problem for the data whose TV is sufficiently small. For general data Riemann problems do not always admit bounded solutions.
However there are certain strictly hyperbolic systems like shallow water which admits bounded solutions for all the Riemann data. Chaplign gas equation does not come under this category. For this system Riemann problems admit bounded solutions for data with small total variation. But not for all Riemann data.
Note: However if we remove strict hyperbolicity assumptions there are systems which do not admit bounded solutions even for the Riemann data whose total variation is small. For example Pressureless gas equation.