I think the main problem here is that "he is sure" is something else than "he is right". He might be 100% sure but still dead wrong, while when there is a 100% chance that he is right, then he is right.
In the sentence you highlighted, he is assuming that his being sure is equivalent to his being right. Of course, a sentence like
> The chance that I am right is 99.3%, so there is only a 0.7% chance that I'm wrong.
is completely correct, but he doesn't know the chance that he is right, he just gives some random, high number to convince you.