When all else fails, draw a diagram.
!Pictures of the tennis ball seam in four orientations
The four diagrams show four different orientations of the tennis ball, where each diagram is obtained from the last by rotating 90° downwards towards you (hence the distinguished endpoints of the arcs A and B). It is easy to see that C, the tennis ball's seam (the U in each diagram), breaks into four identical curves, which are the set of points equidistant between one arc and the endpoint of the other arc.
These arcs are semicircles, and their length is half that of the small circle at 45° N/S latitude. If the tennis ball's radius is 1, the radius of the small circle is $\frac{\sqrt2}2$ and the arc length of each semicircle $\frac{\pi\sqrt2}2$, which means that the seam's total length is $2\pi\sqrt2$. The tennis ball's circumference is $2\pi$, so the ratio asked for in the original question is $\frac{2\pi\sqrt2}{2\pi}=\sqrt2\approx 1.414$.