All you need to do here is substitute in $$16(1/2)^n ~~~~ \textrm{and} ~~~~ 16(1/2)^{n-1}$$ for $a_n$ and $a_{n-1}$, respectively, in the difference equation. You should see that the given choice of $a_n$ follows the rule provided (this is part (i)). Then check that, by plugging in $n = 0$, you indeed find $a_0 = 16$ (this is part (ii)).
Some students find the idea of verifying a solution like this is unintuitive; you start with both the question and the answer - what are you expected to do? It might help to see that another choice of function does $not$ satisfy the equation. Suppose you were told to do the same thing with $$ a_n = 16 + n$$ or $$ a_n = 7(1/2)^n.$$ These are examples of functions that don't solve the equation and initial condition.