You have a Poisson distribution $p(n)$, where $n$ is the number of fish caught in an interval, with a mean per interval (here the rate of fish, i.e. "fish caught per interval, on average") $\mu=\frac{3}{2} \text{ per hour}\times 4 \text{ hours}=6$ when the interval is $4$ hours. Then the probability of catching $n$ fish in the interval is simply $$p(n)=\frac{\mu^n e^{-\mu}}{n!}$$