The _assignment_ function $s$ is a function :
> $s : Var \to D$
where $Var$ is the set of _variables_ : $v_1, v_2, v_3, \ldots, v_k, \ldots$, and $D$ is the _domain_ of the _interpretation_ $I$.
Assume a simple example with $D = \\{ a, b, c, d, ... \\}$ and let $s$ the following assignment :
> $s(v_1)=a, s(v_2)=b, s(v_3)=c$ and $s(u)=d$.
Consider $s'=s[d/2]$, i.e. :
> $s'(v_1)=a, s'(v_2)=d, s(v_3)=c$.
In this case, we have : $k=2$.
What happens if $t$ is $v_3$, i.e. $t$ is $v_j$ with $j=3$ and thus $j \
e k$ ? Clearly, $v_2$ does not occur in $t$; thus, the replacement of each occurrence of $v_2$ in $t$ by $u$ does not produce any change and $t'=t$.
As you can see : $s'(v_3)=c=s(v_3)$ and thus $s'[t]=s'(v_3)=c=s(v_3)=s[t]=s[t']$.