No, $y_2-x'+ a \partial f(y_2)=0$ and $ay'-{x'}+a\partial f(y')=0$ does not imply that $y_2=ay'$. It is true when $f$ is a norm, because then $\partial f(y)=\partial f(ay)$ for all $a>0$.
Here's a simple counterexample. Suppose $f$ is the indicator function of some closed convex set. Then the proximal operator is just the projection onto that set. That is, for some closed convex set $C$ $$ f(x) = \begin{cases} 0 & x \in C \\\ +\infty & x \
otin C \end{cases} $$ Then $\mathrm{Prox}_{af}(x)=\mathrm{Prox}_{f}(x) \in C$. Assume $C$ is not a cone. Then for some $x$ we must have $a \mathrm{Prox}_{f}(x/a) \
otin C$, which means $\mathrm{Prox}_{af}(x) \
e a \mathrm{Prox}_{f}(x/a)$ .