It suffices to show all of $S^2$ is the orbit of a single point, say $e_1$. The equation $Ae_1=x$ says that the first column of $A$ is $x\in S^2$. To create the rest of the matrix $A$, simply take any two vectors on our sphere that are orthogonal to each other and $x$. To do this, compute $e_1\times x$ and then normalize to obtain $y$ for example, then compute $x\times y$ and normalize to obtain $z$. Observe $\det[x~y~z]=\pm1$, so we can permute $y$ and $z$ as necessary to get either $A=[x~y~z]$ or $[x~z~y]$.