There are probably several ways to see this. One way is to realize that the $n$-sphere is homeomorphic to the one point compactification $\mathbb{R}^n\cup\\{\infty\\}$ of $\mathbb{R}^n$ (you can prove this explicitly using the stereographic projection). Now recall that the open unit $n$-disc $D^n$ in $\mathbb{R}^n$ is homeomorphic to $\mathbb{R}^n$. Name this homeomorphism $\phi$. Define the map $$f:D^n/S^{n-1}\to \mathbb{R}^{n}\cup\\{\infty\\}$$ by $\phi$ for all points not on the boundary of $D^n$ and send every point on the boundary $S^{n-1}$ to the point $\infty$. Its easy to show that this map defines a homeomorphism on the quoitient.