Largely coincidence I believe. Structures similar to $\langle x, y\rangle$ had been used for inner product, and $\langle X\rangle$ for expected value of _random variable_ $X$, for _quite_ some time before Dirac adopted the bra$\mid$ket notation for vectors and gave meaning to $\langle \mathsf Q\rangle_\psi = \langle \psi\mid \mathsf Q\mid \psi \rangle$ as the expectation value of _linear operator_ $\mathsf Q$ acting on wave function $\psi$.
For instance, when $\mathsf Q$ is the position operator, then the expected position of a particle with wave function $\psi$ on the $x$-axis is:
$$\langle \psi\mid \mathsf Q\mid \psi \rangle = \int_\Bbb R \psi^\dagger(x)\;x\;\psi(x)\operatorname d x$$
Which coincides neatly with the expression for the expectation of a continuous random variable $X$ that has a probability density function $f$.
$$\langle X \rangle = \int_\Bbb R x\;f(x)\operatorname d x$$