For an exponential with mean $\mu$, the variance is $\mu^2$, so the standard deviation is $\mu$.
b) We want the probability that the duration is $\gt 2.725+2(2.725)$. I expect you can solve this using techniques that you used in a).
c) This asks for the probability a rain event has length $\lt \mu-\mu$, that is, $\lt 0$. That cannot happen.