The Well ordering principle applies to sets of NATURAL numbers, not real numbers. Examples of sets of real numbers without smallest numbers: The set of all even integers (not bounded below). The interval (0,1) (Has 0 as an infinum but no actual smallest element)
If you meant $S$ to be a subset of the natural numbers (Counting numbers), then the usual function we use is $\min S$ to indicate its minimum element, such as $\min \\{1,2, 3\\}=1$
(addendum: The LateX/Jax command is \min)