This is an adverb that means "first(ly)". is a particle that makes the **previous** word adverbial. For example means "eternity" and means "eternally". means "energy/spirit" and means "energetically". Likewise, means "number one" or "the first/top", and is its adverbial version.
Those te-forms are just connecting several actions, namely , , and ().
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He arrived first. / He was the first to arrive.
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The first thing my family do in the morning is gather in the courtyard and do tai chi together.