The root filesystem is passed to the kernel upon boot using the `root` argument. So you should be able to:
cat /proc/cmdline
and then look for `root=/some/path`, or perhaps `root=UUID=longstring`. For instance, I get:
BOOT_IMAGE=/boot/kernel-genkernel-x86_64-4.4.0-sabayon root=UUID=18f3b5a1-3994-43ef-ad6d-cb4c86ff5f95 ro quiet splash
If it's a path, it should point to something recognizable (like /dev/sdb3). If it's a UUID, copy the UUID, and run:
ls -la /dev/disk/by-uuid/[paste UUID here]
That should point to a symlink, like:
lrwxrwxrwx 1 root root 10 Apr 11 22:14 /dev/disk/by-uuid/06699502-fc90-48e4-86c2-cefdaf921e41 -> ../../sda4
Which should tell you which drive it was (in my case, the 4th partition of sda, iow, /dev/sda4)