Just imagine them all placed randomly in a row, their position won't change by extraction
Then P(a black ball is in **any** position) $=\frac{b}{w+b}$,
and P(a white ball is in **any** position) $= \frac{w}{w+b}$.
This directly gives the answer for the first part
* P(get a black ball on i−th extraction) $=\frac{b}{w+b}$
* For P(get a black ball on i−th extraction and white on j−th extraction), the logic is more subtle, the probabilities of a $B-W$ pair occupying any two positions will be the same, hence the same as $B-W$ occupying positions $1$ and $2$, $=\frac{bw}{(b+w)(b+w-1)}$