Consider the kite ($K_4-e$).
The radius $r$ is 1. The diameter is 2.
The center is formed by the two vertices of degree 3, call them $x$ and $y$. The periphery is formed by the two other vertices.
Now $d(x,y)=r=1$, and $x$ is in the center, but $y$ is not in the periphery, it is even in the center.