Consider $G=\mathbb{Z}/2$, it has the presentation $\\{g: g^2=1\\}$. To define $X_G$ one attaches a $2$-cell along the boundary of $S^1$ for the relation $g^2=1$ the resulting space is the projective plane $\mathbb{R}P^2$ whose universal cover $S^2$ is simply connected, but $\pi_2(S^2)=\mathbb{Z}=\pi_2(\mathbb{R}P^2)$. We deduce that $\mathbb{R}P^2$ is not an Eilenberg McLane space.