In answering this type of question, it is often useful to answer the opposite question!
"At least..." immediately suggests multiple routes, with multiple calculations, while "never" is more easily dealt with
So, there is a probability of 22/36 of not succeeding on the first roll of two dice, and again the same probability of not succeeding on the second roll. The probability of failing is thus (22/36)^2. The probability of succeeding is then (1 - 484/1296) or around 0.6265