To show that $(\mathbb{C}, \cdot)$ and $(\mathbb{R}, \cdot)^2$ are not isomorphic as semigroups, observe that both semigroups have a (necessarily unique) annihilator, an element $a$ such that $ax = a$ for any $x$. Both semigroups have a unique element $e$ such that $ex = x$ for any $x \
ot= a$ (in fact the elements other than $a$ form a subsemigroup that is actually a group). The equation $x^2 = e$ has 2 solutions in $(\mathbb{C}, \cdot)$ but 4 solutions in $(\mathbb{R}, \cdot)^2$. Since we can define $a$ and $e$ using only the semigroup operation, the two semigroups cannot be isomorphic.