The physics way I believe is the easier, above geometric methods.
Let four equal forces $F$ act on the center with tetrahedral symmetry. Taking equilibrium of forces along a center-vertex line and its opposite extension:
$$ 3 F \cos \alpha + F = 0; \;\alpha = \cos^{-1} \frac {1}3. $$
where we took $\alpha$ as the acute angle. Required angle is its supplement $$ \approx 109.47^{0}. $$