While Apéry proved in 1978 that $\zeta(3)$ is irrational, the irrationality of $\frac{\zeta(3)}{\pi^3}$ is still an open problem. There are some formulas expressing odd zeta values in terms of powers of $\pi$, the most known ones are due to Plouffe and Borwein & Bradley. Here are some examples:
$$ \begin{aligned} \zeta(3)&=\frac{7\pi^3}{180}-2\sum_{n=1}^\infty \frac{1}{n^3(e^{2\pi n}-1)},\\\ \sum_{n=1}^\infty \frac{1}{n^3\,\binom {2n}n} &= -\frac{4}{3}\,\zeta(3)+\frac{\pi\sqrt{3}}{2\cdot 3^2}\,\left(\zeta(2, \tfrac{1}{3})-\zeta(2,\tfrac{2}{3}) \right). \end{aligned} $$
Moreover, in this Math.SE post we have:
$$ \frac{3}{2}\,\zeta(3) = \frac{\pi^3}{24}\sqrt{2}-2\sum_{k=1}^\infty \frac{1}{k^3(e^{\pi k\sqrt{2}}-1)}-\sum_{k=1}^\infty\frac{1}{k^3(e^{2\pi k\sqrt{2}}-1)}. $$
You can also check out this paper by Vepstas, which provides a nice generalization to some of these identities.