This is almost correct. To use De Moivre's formula you need to get the complex number into polar form (which you have clearly attempted to do). In this case we get $r=\sqrt{1^2+1^2}=\sqrt{2}$ and $\theta=\arctan(1/1)=\pi/4$. Hence $1+i=\sqrt{2}e^{i(\pi/4)}$. Then applying De Moivre's theorem we get:
$$ \begin{split} (1+i)^{100}&=(\sqrt{2}e^{i(\pi/4)})^{100} \\\ &=\sqrt{2}^{100}e^{i(25\pi)} \\\ &=\sqrt{2}^{100}(\cos(25\pi)+i\sin(25\pi)) \end{split} $$