Here's how to do the first one, as an illustration:
Note that the only throws that matter are $2's$ and $7's$, we can disregard the rest. The ordinary probability of getting a $2$ is $\frac 1 {36}$ while the ordinary probability of getting a $7$ is $\frac 6{36}$. Hence, if we only consider those two possibilities the adjusted probability of getting a $2$ is $\frac 17$ while the adjusted probability of getting a $7$ is $\frac 67$.
The problem is now quite simple. The only "winning" path for this bet is the one that starts $2,2$ and the probability of that is $(\frac 17)^2=\frac 1{49}$. that probability corresponds to odds of $48:1$.