Here's one approach:
1. Note that trivially $\vDash p \to p$, so a fortiori $p \vDash p \to p$. But $p \to p \
vDash p$ (suppose $p$ is false). So we can have an instance of $A \vDash B \to C$ without the corresponding $A \to B \vDash C$.
2. Note that trivially $\vDash q \to q$, so a fortiori $p \vDash q \to q$. But of course $p \
vDash q$. So we can have an instance of $A \vDash (B \Rightarrow C)$ without the corresponding $A \vDash C$.