As $k$ is imperfect, say of characteristic $p$, there exists $\alpha\in k$ which is not a $p$-th power in $k$. Consider $K=k[X]/(X^p-\alpha)$. This is a field, finite over $k$, so it defines a regular variety $V$.
Now consider the fiber product $V\times_k V$. Its ring of regular functions is $$K\otimes_k K=K\otimes_k k[X]/(X^p-\alpha)=K[X]/(X^p-\alpha)=K[X]/(X-\theta)^p $$ where $\theta\in K$ is the class of $X$ in $K$. This shows that $V\times_k V$ not regular, it is not even reduced !