In order for the circle to be inside or just touching the edge of a hexagon, the centre of the circle must be inside or on a concentric hexagon whose sides are oriented parallel to the gridlines.
The perpendicular distance from the centre of a side $36$ hexagon to an edge is $18\sqrt{3}$, so subtracting the radius of the circle, the corresponding distance from the centre to an edge of the inner hexagon is $12\sqrt{3}$.
The linear ratio between these similar shapes is therefore $2:3$ and the area ratio is therefore $4:9$.
Thus the probability you seek is the ratio of these areas, i.e. $$\frac 49$$