Reflexivity isn't the right kind of condition for metrizability of the weak topology. Instead we have the following result.
> **Lemma:** Let $X$ be a normed space. The relative weak topology on the unit ball $B_X$ of $X$ is metrizable if and only if $X^*$ is separable.
In particular, if $X$ is reflexive but has non-separable dual then we can conclude that your first claim about boundedness of $S$ being enough in reflexive spaces is false.
It also follows from the lemma that no set with non-empty interior (in the norm topology) can be weakly metrizable if $X^*$ is not separable. If such a set were metrizable, we could fit a homeomorphic image of $B_X$ into it and then, since a subspace of a metrizable space is metrizable, we would have that $B_X$ is metrizable.
In the particular case $X = W^{1,1}(\Omega)$ we have that $X^* = W^{1,\infty}(\Omega)$ is not separable and so $B_X$ (and hence any set with non-empty interior in the norm topology) is not metrizable for the weak topology.