It's a matter of perspective. Most of the chemicals that are addictive to _us humans_ (particularly alkaloids), and may be addictive for some other animals as well, are also insecticides. Lots of plants that we consider poisonous are good food for other species, and lots of plants that insects would consider poisonous are treats for us.
This is a great example of the aimless nature of evolution. The plants that could successfully defend themselves against insects stabilize on a solution that happens to be bad for them in certain ways. Although, you would be hard pressed to find a better way to guarantee reproduction than being addictive to humans.
**Background reference**
* Plant-insect coevolution and inhibition of acetylcholinesterase
* The defensive role of alkaloids in insects and plants
* Exploration of nature's chemodiversity: the role of secondary metabolites as leads in drug development
**Also of interest**
* Bees prefer foods containing neonicotinoid pesticides