Proving "not $P$" can be done by showing two things: "if not $Q$, then not $P$" and "not $Q$". But this is equivalent to proving the contrapositive, "if $P$ then $Q$", along with "not $Q$". The latter is what we call "proof by contradiction" (assuming the opposite).
The Wikipedia article gives a proof of Abel-Ruffini which boils down to "If the Galois group of $S_n$ is not solvable, then general $n^{th}$ degree polynomials are not solvable by radicals", together with "$S_5$ is not a solvable group". This particular proof is not technically "proof by contradiction" (but is equivalent to such a proof).