That's just a starting point; in effect, the proof is basically saying that since $a * (d * e) = a$, then $d * e = 1$ and the only possible values for them are either $d=e=1$ or $d=e=-1$. This in turn shows that $a = \pm b$, given the definitions of $d$ and $e$.
Let's formulate the entire proof in complete sentences, to make it easier to grasp:
**Theorem:** If $a$ and $b$ divide each-other evenly, then $a=\pm b$.
**Proof:**
1. Let $d$ and $e$ be the respective results of evenly dividing $a/b$ and vice versa, i.e. $a = b*d$, $b = a * e$.
2. Next, consider the product $a * (d * e)$. Since $a*(d*e)=a$ (as shown in the question), then we must have $d*e=1$.
3. $d*e=1$ implies that $d=e=\pm 1$, since there are no other numbers that would multiply to $1$.
4. In step 1. we defined $a=b*d$, which with $d=\pm 1$ proves the theorem.