Yes, only a few words ( and ) have i-adjective forms. For others, you can treat them as no-adjectives: (octagonal), (star-shaped), (cylindrical) and so on. (Don't forget ; would mean "starry".)
Also note that and are suitable in everyday conversations but these are not suitable in mathematical contexts. See this answer. The "technical" version for () is / ("circle/circular") or / ("sphere/spherical").
and would mean "octagon-ish" (i.e., something not exactly octagonal).