Plan Scope Management Process (as part of the process group) is mostly concerned about how scope will be managed during the project: after discovering requirements, how it will be decided if they are part of scope or not; how to determine their priority / complexity; and later, how to handle scope changes
PMI suggests to consider those topics in advance, so the scope / requirement management plans must be outlined before starting requirements analysis, scope definition, etc. Of course, it will be refined during planning processes.