No. Take $x_1$ to be a solution of $Ax = b$ and $x_2 \
eq 0$ to be a solution of $Ax = 0$. Then, $x_3 = x_1 + x_2$ is also a solution of $Ax = b$, since $$Ax_3 = A(x_1+x_2) = Ax_1 + Ax_2 = b + 0 = b.$$
No. Take $x_1$ to be a solution of $Ax = b$ and $x_2 \
eq 0$ to be a solution of $Ax = 0$. Then, $x_3 = x_1 + x_2$ is also a solution of $Ax = b$, since $$Ax_3 = A(x_1+x_2) = Ax_1 + Ax_2 = b + 0 = b.$$